Where do I go to volunteer for deployment?

You can do this through Tour of Duty, unfortunately it only works on a government computer so you can't access it from your personal computer even if you have a CAC reader.

Additionally you can reach out to a deploying unit in your State and request to be attached as excess.

With both options you should get with your first line leader and let them know your intentions. When I jumped on as excess for my deployment I had to get approval through my BN CSM before the commander would sign off on transferring me to another unit.

I recommend it, especially as a PFC. You'll get a lot of experience, make connections, and even get some chest candy if that's your thing.

Places you can look without a government computer are:

PFI a program run by DFAS for ADOS orders, they usually will have security jobs at Depots on here you would qualify for.
https://www.dfas.mil/PFI/

A list of FORSCOM taskers you can apply for
https://www.milsuite.mil/book/community/spaces/apf/s1net/forscom-wias

Reserve and guard unit vacancy and mob announcements. Some of these are just places to drill but others will be transfers to prepare for mobilization.
https://www.milsuite.mil/book/community/spaces/apf/s1net/jobannouncementsmobvacancies

no picture and you must be a fool